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The long-range nature of Coulombic interactions between ions means it is likely to be responsible for departures from ideality in ionic solutions and to dominate contributions to non-ideality [23]. This is the basis of the Debye Huckel theory of ionic solutions. However, it generally cannot be used to describe the properties of real solutions above 0.1 mol kg 1 and the effect of complex ion-speci c short-range forces that dominate in solutions at high concentrations must be described empirically [100]. One can treat non-Coulombic interactions of ions in a series expansion of individual ion concentrations analogous to the virial expansion used for studying imperfect gases [28]. In doing this one is trying to model the excess Gibbs free energy of the solution, which leads onto the development of semi-empirical models. They are semi-empirical as short-range interaction forces are dealt with through empirically determined parameters for various systems, whereas the long-range contributions remain theoretical in nature. In solution mixtures of strong electrolytes where association of ions is assumed not to occur, an ion-interaction rather than ion-pairing model is the appropriate choice [101]. The same authors note how Pizter s technique (1975) was the most powerful of these. The theory behind the Pitzer s equations, along with required interaction parameters, is given in

Summary

Empirically supported treatments have taken the clinical psychology professional community by storm in recent years Following the 1995 APA Division 12 (Clinical Psychology) task force report (APA, 1995d), numerous articles have been published about the pros and cons of empirically supported services Nearly all researchers and clinicians would agree that clinical practice should be informed by the best available research evidence However, great controversy exists regarding the ability of empirically supported and manualized treatments to adequately help actual clinical patients who can be highly unique in their biopsychosocial constellation of symptoms, life circumstances, motivation for change, support systems, and so forth In general, many researchers insist that clinical practice should only use empirically supported treatments that closely follow treatment manuals Practitioners generally resist manualized treatments citing the highly unique needs of each client even if they share a similar diagnostic problem (Plante, Boccaccini, & Andersen, 1998).

Recent writings and controversy about empirically supported treatments underscore the historical tensions between researchers (who rarely if ever treat real clinical patients in the real world) and clinicians (who rarely conduct or even read much of the empirical research literature) Research that studies treatment for various clinical problems must use very clear procedures for the selection of patients and therapists, the administration of treatment, and the evaluation of treatment outcome and follow-up Many have argued that the important experimental efforts to conduct high-quality research that maximizes the internal validity of the treatment protocol make it difficult if not impossible to generalize to the real world of clinical work Therefore, efforts to increase internal validity often result in a decrease in external validity.

For example, if we were interested in developing a quality empirically supported treatment for panic disorder, we would want to study those with this condition using a specific treatment protocol David Barlow from Boston University has done exactly this and has published a variety of articles and treatment manuals about panic disorder (eg, Barlow & Craske, 2000) If we used the standard protocol with Mary, the panic patient discussed throughout this text, we would find some difficulties in following the manualized treatment approach For example, in addition to panic, Mary experiences a variety of other concerns and conflicts that need to be addressed when they emerge She may experience a conflict with her husband or son that is not related to her panic symptoms and might wish to discuss them for a number of weeks rather than focusing on.

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experience are involved with helping understand, assess, and treat people with problems in living. Counselors, nurses, psychiatrists, peer helpers, and others are involved with the areas of concern already listed. Clinical psychologists have a doctoral degree from a regionally accredited university or professional school providing an organized, sequential clinical psychology program in a department of psychology (APA, 1981, p. 641). Although many universities offer master s degree training programs in clinical psychology, the doctorate is considered to be the minimal level of training to be considered a clinical psychologist. Clinical psychology is not so much a specialty separate from psychology, but is more a unique application of psychology to the realm of emotional and behavioral problems (Matarazzo, 1987).

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THE DEVELOPMENT OF MODERN PSYCHOLOGY International communication among psychologists has been important to the development of modern psychology. Communication has ourished through world congresses, scholarly exchanges, and perhaps most importantly the establishment of ongoing international organizations. While the chapter by Raymond Fowler and Wade Pickren ( 26) details this development, it is important to highlight here three major international organizations that have played key roles. The oldest international organization of psychologists is the International Association of Applied Psychology (IAAP). The IAAP was founded in 1920 at the rst International Congress of Applied Psychology, convened by E. Clapar de in Geneva. The International Council of Psychologists (ICP) traces its roots to the National Council of Women Psychologists, established in New York City in 1941 by a group of U.S. women psychologists who